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A 25. 00 mL sample of unknown Fe3+ and Cu2+ required 16. 06 mL of 0. 050 8

A 25. 00 mL sample of unknown Fe3+and Cu2+required 16. 06 mL of 0. 050 83 mol·L-1EDTA for complete titrated. A 50. 00 mL sample of unknown was treated with NH4F to protect the Fe3+. Then the Cu2+was reduced and masked by addition of thiourea. Upon addition of 25. 00 mL of 0.050 83 mol·L-1EDTA, the Fe3+was liberated from its fluoride complex and formed an EDTA complex The excess EDTA required 19.77 ml of 0. 01883

mol·L-1Pb2+to reach an endpoint using xylenol orange. Find the concentration of Cu2+in the unknown.

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